Mount data from the Docker on to host

I have built a Python Docker container with option:
VOLUME ["/usr/bin/python3", “/usr/bin/pip”]
What I am trying to do is to mount data from the container (Python binary) on to the host under /usr/bin/ which is read-only itself (CoreOS).
Is there any option to do this with Docker?

No, the only direction you can go is essentially “pushing” files or directories from the host into the container, not the other way.